Wastewater & Effluent Chemical Treatment

pH adjustment

pH adjustment may be required for a number of reasons:

  • To directly precipitate out chemicals otherwise present as more soluble salts
  • To increase the efficacy of any coagulants used
  • To enable discharge limits to be met
  • To maximise the concentration of the most efficient chlorine containing species for disinfection (e.g. hypochlorous acid vs hypochlorite)

The most commonly used chemicals for pH adjustment in effluent plants are lime, sodium hydroxide and sodium bicarbonate.

Product code CompositionComments
HC23An aqueous solution of sodium hydroxide.Concentrated alkaline pH adjuster for many applications including adjusting the pH of waste water.
HC448Sulphuric acidConcentrated acidic pH adjuster for many applications including adjusting the pH of waste water.
HC903Lime suspensionAn alkali for use in pH control of potable water, effluent treatment and flue gas treatment.
HC411Phosphoric acidConcentrated acidic pH adjuster for many applications including adjusting the pH of waste water.
HC228Sodium BicarbonatePowder product for neutralising acid solutions
HC1017Sodium carbonate solutionLiquid product used to increase the alkalinity of waste water.

Coagulants

Many of the solid particles in water are as suspended solids (a colloid). They are very small electrically charged particles which repel each other and will not settle out of suspension by gravity alone in a reasonable timeframe; hence the need for chemical treatment. This typically results in the removal of 80-90% of suspended solids by chemical precipitation.

Coagulants act by neutralising the charge which enables the particles to come together forming slightly larger particles or microflocs.

Traditional coagulants were inorganic compounds, and can have advantages over the inorganic coagulants in that the produced sludge volume is often less, sludge disposal costs can be lower and they are less pH dependent.

Product code CompositionComments
HC784Tannin based coagulantAn aqueous solution of a complex organic polymer coagulant. Particularly appropriate for use in splitting oil- water emulsions. This product is also suitable for use in many applications such as the food industry, oil fields, petrochemical plants and metal working plants.
HC627An aqueous solution of polyaluminium chloride.A cost-effective primary coagulant product. Good insoluble organics removal giving effective BOD/COD reduction. Excellent phosphorous removal. Good colour removal.
HC699Aluminium hydroxide chlorideVersatile product. Intrinsic buffering reduces pH swings. Good organics /colour removal. Also excellent phosphorous removal
HC611Polyaluminium chloride.A cost-effective primary coagulant product. Good insoluble organics removal giving effective BOD/COD reduction. Excellent phosphorous removal. Good colour removal.
HC626Trivalent aluminium enhanced by a powerful, highly charged cationic polymer.Effective BOD/COD removal with good organics/colour removal. An easy to feed liquid which produces lower sludge volumes. Excellent phosphorous removal,
HC390Ferric chlorideEffective in clarification. Reduces phosphate levels. Reduces levels of heavy metals (e.g. lead, coper, cadmium and zinc)
HC417An aqueous solution of ferric ionsEffective BOD/COD removal with good organics/colour removal. Excellent phosphorous removal

Flocculants

The addition of flocculants brings the microflocs into contact resulting in their bonding and formation of flocs which are large enough for them to be separated out from the waste water. The flocculants are organic polymers (generally polyacrylamide) with varying charge densities and molecular weights. They act by forming a “bridge” between the microflocs. Mixing which should be gentle is critical to the performance of the flocculant and is generally done by mechanical or air agitation; overmixing can lead to the breakdown of the flocs.

HydroChemie can supply flocculants in different forms including powders and emulsions in a variety of different molecular weights and charge densities.

Product code CompositionComments
HC600Polyacrylamide in oil based emulsionA low charge density anionic water soluble polymer in oil based emulsion for use as a flocculant across a range of industries
HC601A high molecular weight, medium charge density, anionic latex emulsion polymerEnsures high clarity of the treated water from applications such as: flotation, sedimentation, filtration, thickening, centrifugation and belt pressing.
HC641High charge, high molecular weight cationic polymer. Liquid formulation.A superior quality flocculant for the removal of suspended solids. Suitable for raw water clarification, primary and secondary effluent clarification and oily waste water clarification.
HC796A powder product with a medium anionic charge density and very high molecular weightAn anionic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC610A powder product with very high charge density and molecular weight cationic polymerA superior quality flocculant for the removal of suspended solids. Suitable for raw water clarification, primary and secondary effluent clarification and oil waste water clarification.
HC1023A medium molecular weight anionic copolymer of acrylamide in a water based emulsionAn anionic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC423A high molecular weight anionic copolymer of acrylamide in emulsionA medium charge density anionic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC1081Cationic Polyacrylamide basedUnique, high molecular weight cross linked flocculant of high charge This product is especially effective in those applications where extreme high molecular weight products are needed such as screw presses, centrifuges, and belt filter presses.
HC964A cationic polyacrylamide of very high charge density and high molecular weight in emulsion.A cationic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC1501An anionic polyacrylamide in an aqueous dispersionThe product is a polymer in an aqueous dispersion - free of solvents, oils and surfactants. It provides “a more ecological” way of working" than traditional emulsion products and is also easier to use with increased product stability and without the requirement for specialised make-down equipment.
HC1508An aqueous solution of cationic water soluble polymer in an emulsion.A cationic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC1506A cationic polyacrylamide of very high charge density and high molecular weight in emulsion.A cationic flocculant primarily for use in clarification following coagulation to aid settlement or flotation depending on the treatment process.
HC1521Cationic copolymer of acrylamide and cationic monomer in powder form.A polyelectrolyte for the conditioning of a variety of sludge’s produced in waste-water treatment, prior to mechanical or static dewatering. It is a powder and needs to be prepared, as a solution, before use. Highly effective
--across a wide range of applications including mechanical dewatering, thickening, flotation and clarification. Operates over a wide pH range - typically pH 4-9.

Antifoams

Antifoam agents are often used in both sewage treatment plants as well as in other industrial waste water treatment applications. HydroChemie have a variety of antifoam formulations, both organic and inorganic. A small selection is shown below.

Product code CompositionComments
HC1546Concentrated Silicone emulsionApplied directly to the foam it causes rapid "Foam Kill" whereby the foam collapses. Foam will quickly return unless dosing is continuous at low levels
HC1554Organic based antifoamInhibits the build-up of foams in systems containing proteins, starches, yeasts, synthetic resins and fibrous/particulate materials. Suitable for use in the anaerobic digestion of effluent sludge, fermentation of yeasts, citric acid and other aerobic systems.Suitable for use in recirculating scrubbing systems containing high levels of particulates and electrolytes.
HC617Silicone based antifoam.A concentrated emulsion - acts both as a foam killer and foam preventer. Useful in many applications including waste water process applications.

Odour Control

Odours are not infrequently generated in effluent plants and may be particularly associated with the sludge which contains higher concentrations of odorous chemicals. HydroChemie have a number of products which are able to neutralise many odours such as those associated with hydrogen sulphide, ethylamines, butylamines, mercaptans, fatty acids and ammonia.

Product code CompositionComments
HC623Natural plant oils in aqueous solution.Reacts with odour causing molecules in the gas/vapour phase. Neutralises ammonia, rendering, faecal, indolic, decomposing, sour and fishy odours. Dissipates rapidly, leaving no malodours or fragrance.
HC909Natural plant oils in aqueous solution.Dilute solution of HC623
HC631An aqueous blend of nutrients and anti-sulphides.Blend of nutrients designed to inhibit the conversion of sulphate to sulphide.

Disinfectants

HydroChemie have a number of oxidising biocide products which can be used in disinfection applications.

Product code CompositionComments
HC102Sodium HpochloriteChlorine is able to achieve disinfection goals through bacteria and virus inactivation. Chlorine can also oxidize and degrade soluble contaminants, such as agricultural or pharmaceutical compounds present in wastewater
HC103Hydrogen peroxideHydrogen peroxide is used to reduce the BOD and COD of industrial wastewaters and for the pre-treatment of waters that contain some contaminants that are toxic, inhibitory, or recalcitrant to biological treatment (e.g., pesticides, plasticizers, resins, coolants, and dyestuffs)
HC199% Hydrochloric acidDosed 1:1 with HC123 through a chlorine dioxide generator to produce chlorine dioxide. Chlorine dioxide is effective as both a disinfectant and an oxidant in wastewater treatment where It destroys phenolics, simple cyanides and sulphides by oxidation.
HC123An 8% solution of sodium chloriteDosed 1:1 with HC19 through a chlorine dioxide generator to produce chlorine dioxide. Chlorine dioxide is effective as both a disinfectant and an oxidant in wastewater treatment where It destroys phenolics, simple cyanides and sulphides by oxidation.